Well, what do you want to be able to do? That should help you decide, or help us show you.
How much electrical background do you have? Have you been building circuits on breadboards before? What about other electronics?
If you just need IO pins, get the PCF8574, but if you need analog, then your best bet is probably the PCF8491. Both of these are MUCH MUCH cheaper than the HT prototype board, so if you have a good background, then I would suggest you just get the ICs. You can get them for under $10 (about $3 each, plus shipping).
If you don't have the background, then maybe you should consider the HiTechnic Experimenter's Kit found here
http://www.hitechnic.com/cgi-bin/commer ... ey=NPA1058. With this kit, you should be able to learn quite a lot.
If you are after accomplishing a specific electrical/NXT task, perhaps you could enlighten us a little.
Oh, and BTW, you can use the PCF8574 IC to do IO, and the analog pin on the sensor port as an ADC. In this way, you sort of have one ADC as well as 8 IO lines, and the IC's only cost like $2 each. Please note though, that you can only update/read the 8574 OR read the ADC at a given moment, but you can switch modes fairly quickly.